![]() Notice that the last member of this row is the noble gas krypton ( Z = 36), 4 s 23 d 104 p 6 =, which has filled 4 s, 3 d, and 4 p orbitals. Five 3 d orbitals are filled by the next 10 elements, the transition metals, followed by three 4 p orbitals. Consequently, the electron configuration of potassium, which begins the fourth period, is 4 s 1, and the configuration of calcium is 4 s 2. Accordingly, the 4 s orbital is filled prior to the 3 d orbital because of shielding and penetration effects. The order in which the orbitals are filled is indicated by the diagonal lines running from the upper right to the lower left. Subshells corresponding to each value of n are written from left to right on successive horizontal lines, where each row represents a row in the periodic table. The general order in which orbitals are filled is depicted below. The electron configuration is 3 s 23 p 3. From our theoretical understanding of the electronic structuring of electrons in each element, we will find that these electron configurations are innately related to the structure and organization of The Periodic Table. The process of describing each atom’s electronic structure consists, essentially, of beginning with hydrogen and adding one proton and one electron at a time to create the next heavier element in the table. Quantum numbers and the quantum model that derived them depict our current best understanding of what an atom actually is and how it behaves based on the energetic structure of electrons within it. Beyond their Quantum Mechanical definitions, what do these numbers actually mean, and why are they important to know in a general chemistry course? We know that each electron in an atom is described by a unique set of four quantum numbers: n, l ml, and ms. To write the electron configuration of any element and relate its electron configuration to its position in the periodic table.
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